The boron letters free download






















Find more information on the Altmetric Attention Score and how the score is calculated. The photoelectrochemical PEC performance of g-CN can be enhanced by modifying its photocatalytic properties, which has been considered as a typical challenging agent for water splitting. Here, we present a study of metal-free surface charge transfer doping SCTD of g-CN films by means of surface alteration treatment and accordingly demonstrated its influence on the PEC performance by combining experiments and theoretical calculations.

The as-prepared doped films using a boron dopant boost the photocurrent density by a factor of 3 versus RHE with no sacrificial reagents as compared to pristine g-CN films.

The boron dopant can readily substitute the nitrogen atom when the film is coated five times and, consequently, reduce the band gap by raising the valence band edge. We conjecture that such improvement is due to the effective SCTD and enhanced charge carrier separation, which are beneficial for improving charge migration, charge mobility, space charge region, and recombination rate. Such files may be downloaded by article for research use if there is a public use license linked to the relevant article, that license may permit other uses.

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